Synthèse, Réactivités et Catalyse Organométalliques | SRCO | Institut de Chimie de Strasbourg

The SRCO team broadly aims at the design and reactivity of novel organometallic complexes for small molecules activation (H₂, CO₂) and use in homogeneous catalysis, with a special emphasis on sustainable catalytic processes.

Past/current industrial colloborations: Corbion-Purac Corp. (lactide polymerization), SNF Corp. (biodegradable hydrophilic polymers)

Our team welcomes internship applications at the Master level, potential candidates interested in PhD studies as well as post-doctoral candidates.

Thèmes de recherche

Low-coordinated oxophilic metal species (essentially with groups 2, 12 and 13 metal centers), in particular supported by N-heterocyclic carbenes (NHCs),
Small molecules (H₂, CO₂) activation (H₂, CO₂) with highly electrophilic organometallics based on Al(III), Zn(II) and Mg(II) salts,
Polymerization catalysis of cyclic esters/carbonates using organometallics for the production of biomaterials,
Organometallic complexes of Au(I)/Au(III) for use in homogeneous catalysis.

Enseignement

Vous trouverez ci-dessous les 3 premiers cours M1 du Dr Samuel Dagorne:

Vous trouverez ci-dessous les cours L3 du Dr Samuel Dagorne:

Quelques références marquantes et récentes

G. Printz, D. Ryzhakov , C. Gourlaouen , B. Jacques, S. Messaoudi, F. Dumas, F. Le Bideau, S. Dagorne
First Use of Thiosquaramides as Polymerization Catalysts: Controlled ROP of Lactide Implicating Key Secondary Interactions for Optimal Performance
ChemCatChem 2024, 16 (1), e202301207– DOI : https://doi.org/10.1002/cctc.202301207.

X. Xu, C. Gourlaouen, B. Jacques, S. Dagorne
Robust Two-Coordinate Zn(II) Organocations Supported by Bulky-Yet-Flexible IPr* Carbene: Synthesis, Structure, and Distinct Reactivity in Hydrosilylation Catalysis. Organometallics 2023, 42 (19), 2813–2825– DOI : https://doi.org/10.1021/acs.organomet.3c00282

P. de Frémont, N. Adet, J. Parmentier, X. Xu, B. Jacques, S. Dagorne
Cationic Organometallic Complexes of Group 12 Metals: A Decade of Progress toward the Quest of Novel Lewis Acidic Catalysts
Coordination Chemistry Reviews 2022, 469, 214647– DOI : https://doi.org/10.1016/j.ccr.2022.214647.

J. Tian, Y. Chen, M. Vayer, A. Djurovic, R. Guillot, R. Guermazi, S. Dagorne, C. Bour, V. Gandon
Exploring the Limits of π‐Acid Catalysis Using Strongly Electrophilic Main Group Metal Complexes: The Case of Zinc and Aluminium
Chem. Eur. J. 26 (2020) 12831–12838 – DOI : https://doi.org/10.1002/chem.202001376

N. Adet, D. Specklin, C. Gourlaouen, T. Damiens, B. Jacques, R.J. Wehmschulte, S. Dagorne
Towards Naked Zinc(II) in the Condensed Phase: A Highly Lewis Acidic ZnII Dication Stabilized by Weakly Coordinating Carborate Anions
Angewandte Chemie International Edition, Early view – DOI : https://doi.org/10.1002/anie.202012287

Y.C.A. Sokolovicz, O. Nieto Faza, D. Specklin, B. Jacques, C.S. López, J.H.Z. dos Santos, H.S. Schrekker, S. Dagorne
Acetate-catalyzed hydroboration of CO ₂ for the selective formation of methanol-equivalent products
Catalysis Science & Technology, 10 (2020) 2407–2414 - DOI :https://doi.org/10.1039/D0CY00118J

A.T. Normand, R. Malacea-Kabbara, R. Lapenta, A. Dajnak, P. Richard, H. Cattey, A. Bolley, A. Grassi, S. Milione, A. Auffrant, S. Dagorne, P. Le Gendre
Phosphasalen group IV metal complexes: synthesis, characterization and ring opening polymerization of lactide, Dalton Transactions, 49 (2020) 6989–7004 - DOI :https://doi.org/10.1039/D0DT00972E

C. Romain, S. Bellemin-Laponnaz, S. Dagorne
Recent progress on NHC-stabilized early transition metal (group 3–7) complexes: Synthesis and applications
Coordination Chemistry Reviews, 422 (2020) 213411 - DOI :https://doi.org/10.1016/j.ccr.2020.213411

Bruyere, J.-C.; Specklin, D.; Gourlaouen, C.; Lapenta, R.; Veiros, L. F.; Grassi, A.; Milione, S.; Ruhlmann, L.; Boudon, C.; Dagorne, S.
Cyclic(Alkyl)(Amino)Carbene (CAAC)-Supported Zn Alkyls: Synthesis, Structure and Reactivity in Hydrosilylation Catalysis
Chemistry – A European Journal2019, 25 (34), 8061–8069 - DOI:https://doi.org/10.1002/chem.201900961
Cover feature:S. Dagorne et al.

Bruyere, J.-C.; Gourlaouen, C.; Karmazin, L.; Bailly, C.; Boudon, C.; Ruhlmann, L.; de Frémont, P.; Dagorne, S.
Synthesis and Characterization of Neutral and Cationic Magnesium Complexes Supported by NHC Ligands
Organometallics2019, 38 (14), 2748–2757 - DOI: https://doi.org/10.1021/acs.organomet.9b00304

Dagorne, S.
Recent Developments on N-Heterocyclic Carbene Supported Zinc Complexes: Synthesis and Use in Catalysis
Synthesis2018, 50 (18), 3662–3670 - DOI: https://doi.org/10.1055/s-0037-1610088

Dagorne, S. Wehmschulte, R.
Recent Developments on the Use of Group 13 Metal Complexes in Catalysis
ChemCatChem2018, 10 (12), 2509–2520 - DOI:http://onlinelibrary.wiley.com/doi/pdf/10.1002/cctc.201800045

D. Specklin, F. Hild, C. Fliedel, C. Gourlaouen, L. F. Veiros, S. Dagorne
Accessing Two‐Coordinate Zn^II Organocations by NHC Coordination: Synthesis, Structure, and Use as π‐Lewis Acids in Alkene, Alkyne, and CO₂ Hydrosilylation
Chem. Eur. J. 2017, 23, 15908-15912- DOI:https://onlinelibrary.wiley.com/doi/abs/10.1002/chem.201704382

D. Specklin, C. Fliedel, C. Gourlaouen, J.-C. Bruyere, T. Avilés, C. Boudon, L. Ruhlmann, S. Dagorne
N‐Heterocyclic Carbene Based Tri‐organyl‐Zn–Alkyl Cations: Synthesis, Structures, and Use in CO₂ Functionalization
Chem. Eur. J. 2017, 23, 5509-5519 - DOI:https://www.onlinelibrary.wiley.com/doi/abs/10.1002/chem.201605907

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