Coordination, Ligands, Interactions et Catalyse | CLIC | Institut de Chimie de Strasbourg

Preparation and studies of coordination complexes and control of their properties via the use of rigid and semi-rigid ligands,
Synthesis of molecular materials based on tetrapyrrolic macrocycles,
Energy and electron transfers in supramolecular scaffolds,
Study of sigma-hole interactions (halogen and chalcogen bonds) in solution,
Halogen/Chalcogen bond catalysis,
Synthesis of chiral and luminescent organometallic cyclotribenzylenes and metallo-cryptophanes for the detection of small molecules,
Development of hydroxamate-type ligands specific for lanthanides and actinides for applications in nuclear medicine.

Keywords: Molecular materials, Self-assembly, Molecular electronics, Surface organization, Weak interactions, Porphyrins, Bipyridines, Cyclophanes, Sigma-Hole, Catalysis, Chalcogen Bond, Metallo-cryptophanes, Chelators for medical imaging, radiotherapy and therapy with actinide chelators.

Selection of key publications

Recent reviews:

V. Mamane
Organocatalyse par Liaison Halogène et Chalcogène.
L'Act. Chim.2024, 497, 26-29 (N°497, Septembre 2024)

P. Pale, V. Mamane
Chalcogen bonding catalysis: tellurium, the last frontier?
Chem. Eur. J.2023, 29, e202302755

P. Pale, V. Mamane
Chalcogen Bonds: How to Characterize Them in Solution?
ChemPhysChem2023, 24, e202200481

M. Vonesch, J. A. Wytko, H. Kitagishi, K. Kano, J. Weiss
Modelling haemoproteins: porphyrins and cyclodextrins as sources of inspiration
Chem. Commun. 2019, 55, 14558-14565

J. A. Wytko, R. Ruppert, C. Jeandon and J. Weiss
Metal-mediated linear self-assembly of porphyrins
Chem. Commun.(Feature Article), 2018, 54, 1550-1558

Recent articles:

F. Mangin, O. Fonquernie, P. Jewula, S. Brandès, M.-J. Penouilh, Q. Bonnin, B. Vincent, E. Espinosa, E. Aubert, M. Meyer, J.-C. Chambron
Combining desferriferrioxamine B and 1-hydroxy-2-piperidone ((PIPO)H) to chelate zirconium. Solution structure of a model complex of the [⁸⁹Zr]Zr–DFOcyclo*–mAb radioimmunoconjugate
ChemPlusChem2024, 89, e202400062.

J. Zhang, N. Zorn, E. Leize-Wagner, M. Jean, N. Vanthuyne, E. Espinosa, E. Aubert,B. Vincent, J.-C. Chambron
Cyclotribenzylene alkynylgold(I) phosphine complexes: Synthesis, chirality, and exchange of phosphine
Dalton Trans.2024, 53, 5521–5533.

L. Groslambert, Y. Cornaton, M. Ditte, E. Aubert, P. Pale, A. Tkatchenko, J.-P. Djukic, V. Mamane
Affinity of Telluronium Chalcogen Bond Donors for Lewis Bases in Solution: A Critical Experimental-Theoretical Joint Study
Chem. Eur. J.2024, 30, e202302933.

P. Peluso, V. Mamane, Y. Spissu, G. Casu, A. Dessì, R. Dallocchio, B. Sechi, G. Palmieri, C. Rozzo
Iodinated 4,4’-bipyridines with antiproliferative activity against melanoma cell lines
ChemMedChem2024, 19, e202300662

L. Groslambert, P. Pale, and V. Mamane
Telluronium-Catalyzed Halogenation Reactions: Chalcogen-Bond Activation of N-Halosuccinimides and Catalysis
Chem. Eur. J.2024, 30, e202401650

J. Joseph, J. Raya, F. Palmino, J. Jeannoutot, M. Berville, J. Weiss, F. Chérioux, J. A. Wytko
Self-assembled viologens on HOPG: Solid-state NMR and AFM unravel the location of the anions
Nanoscale, 2024, 16, 13089-13095

X. Yao, M. Vonesch, J. Wytko, J. Weiss, X. Sun, J.-C. Lacroix
Reliable I/V characteristics and long lifetime of porphyrin-based single-molecule junctions.”
J. Mater. Chem. C, 2024, 12, 4326-4335

R. Weiss, E. Aubert, L. Groslambert, P. Pale, V. Mamane
Evidence for and evaluation of fluorine–tellurium chalcogen bonding
Chem. Sci.2023, 14, 7221-7229

M. Berthe, Y. Kagawa, A. Riquet, T. Hayashi, J. Weiss, J. A. Wytko
Remote template effect in the synthesis of bipyridine-strapped porphyrins
Chem. Commun. 2023, 59, 6718-6721. DOI: 10.1039/D3CC01697H

J. Zhang, F. Aribot, J.-C. Chambron, N. Zorn, E. Leize-Wagner, M. Jean, N. Vanthuyne, E. Espinosa, E. Aubert
Organoplatinum-bridged cyclotribenzylene dimers
Eur. J. Inorg. Chem.2023, e202300284, 1-15

P. Jewula, M. Grandmougin, M. Choppin, A. M. C. Tivelli, A. Amati, Y. Rousselin, L. Karmazin, J.-C. Chambron, M. Meyer
Complexes of Fe(III) and Ga(III) derived from the cyclic 6- and 7-membered hydroxamic acids found in mixed siderophores
Eur. J. Inorg. Chem.2023, 26, e202300038, 1-11

D. S. Abou, M. Longtine, A. Fears, N. Benabdallah, R. Unnerstall, H. Johnston, K. Shim, A. Hasson, H. Zhang, D. Ulmert, F. Mangin, S. Ozen, L. Raibaut, S. Brandès, M. Meyer, J.-C. Chambron, D. S. Tatum, D. Magda, R. L. Wahl, D. L. J. Torek
Evaluation of candidate theranostics for ²²⁷Th/⁸⁹Zr paired radioimmunotherapy of lymphoma
J. Nucl. Med.2023, 64, 1062-1068

J. Joseph, P. Mobian, A. Chaumont, J. A. Wytko, J. Weiss
Going up the ladder: Stacking four 4,4’-bipyridine moieties within a Ti(IV)-based tetranuclear architecture
Inorg. Chem. 2022, 61, 16448-16457. DOI: https://doi.org/10.1021/acs.inorgchem.2c02566

J. Zhang, A. Schaly, J.-C. Chambron, B. Vincent, N. Zorn, E. Leize-Wagner, M. Jean, N. Vanthuyne
Alkynylgold(I) C₃-chiral concave complexes: Aggregation and luminescence
Chem. Eur. J.2022, 28, e202103759, 1-14

F. Schleife, C. Bonnot, J.-C. Chambron, M. Börner, B. Kersting
Expanding mercaptocalixarenes: A new kind of macrocyclic ligands for stabilization of polynuclear thiolate clusters
Chem. Eur. J.2022, 28, e20210455, 1-12

R. Weiss, E. Aubert, P. Pale, V. Mamane
Chalcogen-Bonding Catalysis with Telluronium Cations
Angew. Chem. Int. Ed. 2021, 60, 19281-19286

M. Hananaa, C. Kahlfuss, J. Weiss, R. Cornut, B. Jousselme, J. A. Wytko, S. Campidelli
ORR activity of metalated phenanthroline-strapped porphyrin adsorbed on carbon nanotubes
C. R. Chimie2021, (3) 1-8; DOI:: https://doi.org/10.5802/crchim.86

J. Richard, J. Joseph, C. Wang, A. Ciesielski, J. Weiss, P. Samorì, V. Mamane, J. A. Wytko
Functionalized 4,4-Bipyridines: Synthesis and 2D Organization on Highly Oriented Pyrolytic Graphite
J. Org. Chem.2021, 4, 3356-3366

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