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Actualités de l'institut

févr. 26 2024


Abstract Molecular triangles with competing Heisenberg interactions and significant Dzyaloshinskii–Moriya interactions (DMI) exhibit high environmental sensitivity, making them potential candidates for active elements for quantum sensing. Additionally, these triangles exhibit magnetoelectric coupling, allowing their properties to be controlled using electric fields. However, the manipulation and...[En savoir plus]

févr. 12 2024


Abstract The design of enantiomerically pure circularly polarized luminescent (CPL) emitters would enormously benefit from the accurate and in-depth interpretation of the chiroptical properties by means of jointly (chiroptical) photophysical measurements and state-of-the-art theoretical investigation. Herein, computed and experimental (chiro-)optical properties of a series of eight enantiopure...[En savoir plus]

févr. 6 2024

Batteries and Supercaps [POMAM]

Graphical Abstract: A metal-free porphyrin (TDPP) with a diphenylamino-Phenyl group is proposed as an electrode for aluminum-based batteries. The electrochemical performance is explored thoroughly. The extended porphyrin conjugated structure by the diphenylamino-phenyl groups shows a reversible capacity of 83 mAh g−1 at 1 A g−1 after 200 cycles and good cycling stability.   Reference...[En savoir plus]

janv. 30 2024

Redox-Active Ligands: Nouveau livre édité par M. Desage-El Murr [OMECA]

L'Institut de Chimie de Strasbourg est heureux de vous informer de la parution du livre Redox-Active Ligands: Concepts and Catalysis, édité par Marine Desage-El Murr (équipe OMECA), et tout juste publié chez Wiley (lien). The book Redox-Active Ligands: Concepts and Catalysis, edited by Marine Desage-El Murr (OMECA team), has just been published by Wiley (link).   DESCRIPTION Redox-Active...[En savoir plus]

janv. 8 2024

Org. Biomol. Chem. [SOPhy]

Abstract We developed a chemoselective metal-free access for the 1,2- and 2,3-semireduction of CF3-N-allenamides. The enamide functionality of CF3-substituted N-allenamides could be efficiently reduced by Et3SiH/BF3·OEt2 in total regioselectivity and good stereoselectivity, whereas DBU promoted the isomerization of the resulting allyl amide leading exclusively to the E-configurated...[En savoir plus]

déc. 20 2023

Chemistry—A European Journal [ECMC]

Graphical Abstract Two for the price of one! Depending on the experimental conditions, two dramatically different diphosphanes can be obtained from diphenyl(2-phosphanylphenyl)phosphane and an α-cyclodextrin-derived dimesylate. The metal confining properties of the cavity-shaped ligands have been exploited to produce luminescent chelate [CuX(PP)] complexes (X=Cl, Br,...[En savoir plus]

déc. 18 2023

Soutenance de thèse de doctorat de Zhiwei CAI

Lundi 18 décembre à 14h00, Salle Kern (2ème étage), Faculté de Chimie, 1 Rue Blaise Pascal, 67000 Strasbourg. Titre: "New materials based on doped polyoxotitanates (POTs) or based on titanium (IV) and silver (I) salicylate complex." Ce travail a été effectué sous la direction du Professeur Laurent RUHLMANN et du Professeure Corinne Boudon (Laboratoire d'Electrochimie et de Chimie Physique du...[En savoir plus]