Abstract
FID-detected nutations of the antiferromagnetic crystal form of [Y(pc)2]˙ demonstrated that its radical spin can be coherently driven in its magnetically condensed undeuterated phase and at room temperature. Liquid-helium nutations revealed additional Rabi oscillations assigned to transitions within higher-multiplicity states of finite-sized chain fragments.
Reference
Athanassios K. Boudalis, Jorge-Enrique Olivares-Peña, Eufemio Moreno-Pineda, Artem Fediai, Wolfgang Wenzel, Philippe Turek and Mario Ruben
Room-temperature spin nutations in a magnetically condensed phase of [Y(pc)2]˙
Chem. Commun. , 2021 - DOI: https://doi.org/10.1039/D1CC05491K
Contact
Athanassios K. Boudalis (https://pomam.chimie.unistra.fr/aboudalis/), POMAM, Institut de Chimie (UMR 7177).
