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[CLIC] Coordination, Ligands, Interactions et Catalyse

Head of the research group

Victor MAMANE
Directeur de recherche au CNRS

Year of creation of the group - 2024 (Formerly CLAC)

Location

Le Bel Institute, 8th floor South

Secretarial and accounting services provided by

Agnès REIFFSTECK
email : reiffste@unistra.fr
Phone : +33 (0)3 68 85 14 32

Permanent members

  • Christophe JEANDON
    Maître de conférence à l'Unistra
    email: cjeandon@unistra.fr
    Phone :+33 (0)3 68 85 17 18
  • Jean WEISS
    Directeur de recherche CNRS
    email : jweiss@unistra.fr
    Phone : +33 (0)3 68 85 14 23
  • Victor MAMANE
    Directeur de recherche CNRS
    email: vmamane@unistra.fr
    Phone:+33(0)3 68 85 17 00
  • Jennifer WYTKO
    Chargé de recherche CNRS
    email: jwytko@unistra.fr
    Phone : +33 (0)3 68 85 14 24
  •  Jean-Claude CHAMBRON
    Directeur de recherche CNRS
    email: jcchambron@unistra.fr
    Phone: +33 (0)3 68 85 15 34
  

Non-permanent members

PhD students

  • Mathilde BERTHE
  • Eléanna NIKOLOPOULOS
  • Loic GROSLAMBERT (Co-supervision with COSyS team))
  • Laurie ZUJEW


Research topics

Our activities are focused on:

  • Preparation and studies of coordination complexes and control of their properties via the use of rigid and semi-rigid ligands,
  • Synthesis of molecular materials based on tetrapyrrolic macrocycles,
  • Energy and electron transfers in supramolecular scaffolds,
  • Design and study of heme protein models,
  • Study of sigma-hole interactions (halogen and chalcogen bonds) in solution,
  • Halogen/Chalcogen bond catalysis,
  • Synthesis of chiral and luminescent metallo-cryptophanes for the detection of small molecules,
  • Development of hydroxamate-type ligands specific for lanthanides and actinides for applications in nuclear medicine.

Keywords: Molecular materials, Self-assembly, Molecular electronics, Surface organization, Weak interactions, Porphyrins, Bipyridines, Cyclophanes, Sigma-Hole, Catalysis, Chalcogen Bond, Metallo-cryptophanes, Chelators for medical imaging and radiotherapy.

 

drawing theme

Selection of key publications

Recent reviews:

P. Pale, V. Mamane
Chalcogen bonding catalysis: tellurium, the last frontier?
Chem. Eur. J. 2023, 29, e202302755. DOI: https://doi.org/10.1002/chem.202302755

P. Pale, V. Mamane
Chalcogen Bonds: How to Characterize Them in Solution?
ChemPhysChem 2023, 24, e202200481. DOI: https://doi.org/10.1002/cphc.202200481

M. Vonesch, J. A. Wytko, H. Kitagishi, K. Kano, J. Weiss
Modelling haemoproteins: porphyrins and cyclodextrins as sources of inspiration
Chem. Commun. 2019, 55, 14558-14565. DOI: https://doi.org/10.1039/C9CC07545C

J. A. Wytko, R. Ruppert, C. Jeandon and J. Weiss
Metal-mediated linear self-assembly of porphyrins
Chem. Commun. (Feature Article), 2018, 54, 1550-1558  DOI: https://doi.org/10.1039/C7CC09650J

Recent articles:

L. Groslambert, Y. Cornaton, M. Ditte, E. Aubert, P. Pale, A. Tkatchenko, J.-P. Djukic, V. Mamane,
Affinity of Telluronium Chalcogen Bond Donors for Lewis Bases in Solution: A Critical Experimental-Theoretical Joint Study
Chem. Eur. J. 2024, 30, e202302933. DOI:https://doi.org/10.1002/chem.202302933

R. Weiss, E. Aubert, L. Groslambert, P. Pale, V. Mamane,
Evidence for and evaluation of fluorine–tellurium chalcogen bonding
Chem. Sci. 2023, 14, 7221-7229. DOI: https://doi.org/10.1039/D3SC00849E

M. Berthe, Y. Kagawa, A. Riquet, T. Hayashi, J. Weiss, J. A. Wytko
Remote template effect in the synthesis of bipyridine-strapped porphyrins
Chem. Commun. 2023, 59, 6718-6721. DOI :10.1039/D3CC01697H

J. Zhang, F. Aribot, J.-C. Chambron, N. Zorn, E. Leize-Wagner, M. Jean, N. Vanthuyne, E. Espinosa, E. Aubert,
Organoplatinum-bridged cyclotribenzylene dimers
Eur. J. Inorg. Chem. 2023, e202300284, 1-15. DOI: https://doi.org/10.1002/ejic.202300284

P. Jewula, M. Grandmougin, M. Choppin, A. M. C. Tivelli, A. Amati, Y. Rousselin, L. Karmazin, J.-C. Chambron, M. Meyer,
Complexes of Fe(III) and Ga(III) derived from the cyclic 6- and 7-membered hydroxamic acids found in mixed siderophores
Eur. J. Inorg. Chem. 2023, 26, e202300038, 1-11. DOI: https://doi.org/10.1002/ejic.202300038

D. S. Abou, M. Longtine, A. Fears, N. Benabdallah, R. Unnerstall, H. Johnston, K. Shim, A. Hasson, H. Zhang, D. Ulmert, F. Mangin, S. Ozen, L. Raibaut, S. Brandès, M. Meyer, J.-C. Chambron, D. S. Tatum, D. Magda, R. L. Wahl, D. L. J. Torek,
Evaluation of candidate theranostics for 227Th/89Zr paired radioimmunotherapy of lymphoma
J. Nucl. Med. 2023, 64, 1062-1068. DOI: https://doi.org/10.2967/jnumed.122.264979

J. Joseph, P. Mobian, A. Chaumont, J. A. Wytko, J. Weiss
Going up the ladder: Stacking four 4,4’-bipyridine moieties within a Ti(IV)-based tetranuclear architecture
Inorg. Chem. 2022, 61, 16448-16457. DOI:  https://doi.org/10.1021/acs.inorgchem.2c02566

J. Zhang, A. Schaly, J.-C. Chambron, B. Vincent, N. Zorn, E. Leize-Wagner, M. Jean, N. Vanthuyne
Alkynylgold(I) C3-chiral concave complexes: Aggregation and luminescence
Chem. Eur. J. 2022, 28, e202103759, 1-14. DOI: https://doi.org/10.1002/chem.202103759

F. Schleife, C. Bonnot, J.-C. Chambron, M. Börner, B. Kersting
Expanding mercaptocalixarenes: A new kind of macrocyclic ligands for stabilization of polynuclear thiolate clusters
Chem. Eur. J. 2022, 28, e20210455, 1-12. DOI: https://doi.org/10.1002/chem.202104255

R. Weiss, E. Aubert, P. Pale, V. Mamane,
Chalcogen-Bonding Catalysis with Telluronium Cations
Angew. Chem. Int. Ed. 2021, 60, 19281-19286. DOI: https://doi.org/10.1002/anie.202105482

M. Hananaa, C. Kahlfuss, J. Weiss, R. Cornut, B. Jousselme, J. A. Wytko, S. Campidelli
ORR activity of metalated phenanthroline-strapped porphyrin adsorbed on carbon nanotubes
C. R. Chimie 2021, (3) 1-8; DOI:: https://doi.org/10.5802/crchim.86

J. Richard, J. Joseph, C. Wang, A. Ciesielski, J. Weiss, P. Samorì, V. Mamane, J. A. Wytko
Functionalized 4,4-Bipyridines: Synthesis and 2D Organization on Highly Oriented Pyrolytic Graphite
J. Org. Chem. 2021, 4, 3356-3366. DOI: https://doi.org/10.1021/acs.joc.0c02708

R. Raavé, G. Sandker, P. Adumeau, C. B. Jacobsen, F. Mangin, M. Meyer, M. Moreau, C. Bernhard L. Da Costa, A. Dubois, V. Goncalves, M. Gustafsson, M. Rijmkema, O. Boerman, J.-C. Chambron, S. Heskamp, F. Denat,
Direct comparison of the in vitro and in vivo stability of DFO, DFO* and DFOcyclo* for 89Zr-immunoPET
Eur. J. Nucl. Med. Mol. Imaging 2019, 46, 1966-1977. DOI: https://10.1007/s00259-019-04343-2

A. Schaly, M. Meyer, J.-C. Chambron, M. Jean, N. Vanthuyne, E. Aubert, E. Espinosa, N. Zorn, E. Leize-Wagner
The chemo- and stereoselective formation of pallado- and platinocryptophanes
Eur. J. Inorg. Chem. 2019, 2691-2706. DOI: https://doi.org/10.1002/ejic.201900230