Chem. Eur. J./ Cover [POMAM]

Graphical Abstract

An asymmetric diradical was synthesized by grafting a nitroxide radical onto the [Y(Pc)₂]⋅ radical system. The molecule was shown to exhibit a weak exchange interaction between its two radical units. The g-asymmetry combined with the magnetic interaction led to the electron paramagnetic resonance transition of different tipping angles, which could be selectively enhanced by proper choice of applied magnetic field and microwave power.

 

Reference

Selective Transition Enhancement in a g-Engineered Diradical

Joe Komeda, Athanassios K. Boudalis, Nicolas Montenegro-Pohlhammer, Cyril Antheaume, Asato Mizuno, Philippe Turek, Mario Ruben

Chem. Eur. J., First published: 02 April 2024 – DOI: https://doi.org/10.1002/chem.202400420

 

Contact

Athanassios K. Boudalis , team POMAM, Institut de Chimie (UMR 7177).