The introduction of nanoparticles (MNPs) at the surface of cationic poly-porphyrin films, obtained by electrostatic interaction between the bis-porphyrin copolymer and the Preyssler type polyoxometalate P5W30@MNPs, enhances the photocurrent (up to 2.5-3 times greater as a function of the used nanoparticle).
Enhancement of photocurrent by incorporation of Preyssler type polyoxometalate protected nanoparticles in polyporphyrin films
Chem. Comm. Advance article - DOI: https://doi.org/10.1039/D0CC06283A
C. Boudon, V. Badets, A. Bonnefont and L. Ruhlmann, équipe LECPCS, Institut de Chimie (UMR 7177).