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Feb 8 2021

J. Org. Chem. [CLAC/LASYROC/ISIS]

Abstract : Commercial 4,4′-bipyridine is a popular scaffold that is primarily employed as a linker in 3D self-assembled architectures such as metallo-organic frameworks or as a connector in 2D networks. The introduction of alkyl substituents on the bipyridine skeleton is instrumental when 4,4′-bipyridines are used as linkers to form 2D self-assembled patterns on surfaces. Here, several synthetic...[more]

Feb 4 2021

Chem. Comm. [LECPCS]

Abstract: The introduction of nanoparticles (MNPs) at the surface of cationic poly-porphyrin films, obtained by electrostatic interaction between the bis-porphyrin copolymer and the Preyssler type polyoxometalate P5W30@MNPs, enhances the photocurrent (up to 2.5-3 times greater as a function of the used nanoparticle). Graphical Abstract :   Reference : Enhancement of photocurrent by...[more]

Feb 4 2021

Electrochimica Acta [LECPCS]

Abstract:   Four hybrid polyoxometalate–porphyrin copolymer films were obtained by the electrooxidation of zinc-β-octaethylporphyrin (ZnOEP) or 5,15-ditolylporphyrin (H2T2P) in the presence of organosilyl functionalized Keggin-type POMs TBA3[PW11Si2O40C26H16N2] (abbreviated Py-PW11Si2-Py) and Dawson-type POMs TBA6[P2W17Si2O62C26H16N2] (abbreviated Py-P2W17Si2-Py) bearing two remote pyridyl...[more]

Feb 4 2021

Chem. Comm. [LECPCS]

Abstract: Two novel polyoxovanadate-iodoBodipy supramolecular assemblies, named as (2I-BDP-C6)2V6 and (2I-BDP-C6)3V10, were first synthesized by self-assembly of anionic hexavanadate and decavanadate with cationic iodoBodipy for photochemotherapy, respectively. The mechanisms for synergistic photochemotherapy of anion-cation pairs were forced on. In particular, (2I-BDP-C6)3V10 is the first...[more]

Feb 4 2021

ChemSusChem [LECPCS]

Abstract: A new green synthetic route to tris[4‐(3,4‐ethylenedioxythiophene)phenyl]amine (TEPA) monomer has been developed and the molecular structure of TEPA has been determined by using single‐crystal XRD. Solution‐processable nanoporous poly{tris[4‐(3,4‐ethylenedioxythiophene)phenyl]amine} (PTEPA) is prepared by a chemical oxidative polymerization in a microemulsion. Based on the distorted...[more]

Feb 4 2021

ChemSusChem [LECPCS]

Abstract: Iron-containing sludges (DW/Fe) were prepared by the electroflocculation of industrial printing and dyeing wastewater (DW). To investigate the formation process and the properties of the DW/Fe sludges and their application in anode materials in Li-ion batteries, the DW/Fe sludges were compared to three other sludges (MB/Fe, RB/Fe, Ta/Fe) prepared from model solutions that contained...[more]

Feb 4 2021

ACS Catal. [LECPCS]

Abstract: Nickel is a very abundant transition metal in the Earth’s crust, and it finds numerous applications in electrochemical processes where metallic Ni or its oxides are thermodynamically stable, particularly in alkaline environments. This contribution addresses electrocatalytic properties of Ni-based catalysts in reactions of fuel oxidation in alkaline media. It first details the...[more]