- Presentation
- Research Groups
- Biogéochimie moléculaire
- [BCB] Biométaux et Chimie Biologique
- [CLIC] Coordination, Ligands, Interactions et Catalyse
- [CBMB] Chimie et Biochimie de Molécules Bioactives
- [LCQS] Chimie Quantique de Strasbourg
- [LECPCS] Electrochimie et Chimie Physique du Corps Solide
- [COSyS] Catalyse Organométallique, Synthèse organique et Santé
- [SOPhy] Synthèse Organique & Phytochimie
- [LSAMM] Synthèse des Assemblages Moléculaires Multifonctionnels
- [LCSOM] Chimie et Systémique Organo-Métalliques
- [CBAT] Chimie Biologique et Applications Thérapeutiques
- [ECMC] Confinement Moléculaire et Catalyse
- [POMAM] Propriétés Optiques et Magnétiques des Architectures Moléculaires
- Biophysique des membranes et RMN
- [IFM] Laboratoire d’Ingénierie des Fonctions Moléculaires
- [SRCO] Synthèse, Réactivité et Catalyse Organométalliques
- [OMECA] Objets, MEtaux et CAtalyse
- [SOCAT] Synthèse Organométallique et CATalyse
- Scientific Services
- News
- Conferences
- CNRS and University directories
News
Chemical Science [LASYROC]
Abstract In the field of noncovalent interactions, chalcogen bonding (ChB) involving the tellurium atom is currently attracting much attention in supramolecular chemistry and in catalysis. However, as a prerequisite for its application, the ChB should be studied in solution to assess its formation and, if possible, to evaluate its strength. In this context, new tellurium derivatives bearing CH2F...[more]
Chemistry – A European Journal [LASYROC]
Abstract Telluronium salts bearing electron-withdrawing groups were prepared, and their ability to drive chalcogen bonds with ketones and imines was demonstrated in the solid state and in solution. These strong σ-hole bond donors were able to efficiently catalyze the Povarov reaction through chalcogen bond activation of imines and subsequent reaction with alkenes. The title reaction was found to...[more]
Nature [Biogéochimie Moléculaire]
Abstract Eukaryotic life appears to have flourished surprisingly late in the history of our planet. This view is based on the low diversity of diagnostic eukaryotic fossils in marine sediments of mid-Proterozoic age (around 1,600 to 800 million years ago) and an absence of steranes, the molecular fossils of eukaryotic membrane sterols1,2. This scarcity of eukaryotic remains is difficult to...[more]
Prix du meilleur Poster pour Paula Milán Rodríguez [IFM]
L'Institut de Chimie de Strasbourg (UMR 7177) a le plaisir de vous informer que Paula Milán Rodríguez (équipe IFM dirigée par M. Cecchini) s'est vu remettre le prix du meilleur Poster à l'occasion du XXIIIème Congrès du Groupe de Graphisme et Modélisation Moléculaire (GGMM) qui s’est déroulé à Toulouse du 15-17 Mai 2023 : https://ggmmfr.wordpress.com/ Téléchargement du poster: "Markov State...[more]
J. Am. Chem. Soc. [LSAMM, LCQ]
Abstract A multi-responsive receptor consisting of two (acridinium-Zn(II) porphyrin) conjugates has been designed. The binding constant between this receptor and a ditopic guest has been modulated (i) upon addition of nucleophiles converting acridinium moieties into the non-aromatic acridane derivatives and (ii) upon oxidation of the porphyrin units. A total of eight states has been probed for...[more]
Organic Geochemistry [Biogéochimie Moléculaire]
Abstract Lipid biomarkers, such as the various bacteriohopanetetrol (BHT) isomers studied here, are useful tools in tracing bacterially mediated nitrogen and carbon cycle processes affecting greenhouse gas emissions, including the anaerobic oxidation of ammonia. Three BHT isomers occur commonly in the environment. By gas chromatography, BHT-34S elutes first; it is produced by numerous bacteria....[more]
Chemical Communications [CLAC]
Abstract A bipyridine-strapped porphyrin was prepared using a remote template effect of alkali or transition metal cations in the bipyridine subunit to enhance the yield 10-fold. The flexibility of the bipyridine-strap also allowed the synthesis of a doubly strapped porphyrin. Reference Remote template effect in the synthesis of bipyridine-strapped porphyrins M. Berthe, Y. Kagawa, A....[more]