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Publications récentes

mai 23 2023

Chemical Communications [CLAC]

Abstract A bipyridine-strapped porphyrin was prepared using a remote template effect of alkali or transition metal cations in the bipyridine subunit to enhance the yield 10-fold. The flexibility of the bipyridine-strap also allowed the synthesis of a doubly strapped porphyrin. Reference Remote template effect in the synthesis of bipyridine-strapped porphyrins M. Berthe, Y. Kagawa, A....[En savoir plus]

mai 23 2023

Eur. J. Inorg. Chem. [CLAC]

Abstract Six- and seven-membered cyclic hydroxamic acids are found as terminal binding units in different families of siderophores, including exochelins and mycobactins. The simplest models of these preorganized chelating ligands were known, but their coordination chemistry with Fe3+, the target metal ion of siderophores, had never been reported. Four complexes were synthesized and studied: two...[En savoir plus]

mai 23 2023

Chemistry - A European Journal [LCSOM]

Abstract The   performance   of   six   newly   synthesized benzo[h]quinoline-derived  acetonitrilo  pentamethylcyclopentadienyl iridium(III) tetrakis(3,5-bis-trifluoromethylphenyl)borate salts bearing different substituents -X (-OMe, -H, -Cl, -Br, -NO2 and –(NO2)2) on the heterochelating ligand were evaluated in the dehydro-O-silylation of   benzyl   alcohol   and   the   monohydrosilylation  ...[En savoir plus]

mai 22 2023

Nouvel ouvrage : Matière et complexité, éditions Atlande [LCQ]

Nouvel ouvrage paru aux éditions Atlande pour Vincent Robert (équipe LCQ, Institut de Chimie de Strasbourg, UMR 7177), où les auteurs discutent de la "Compléxité": https://www.atlande.eu/forum/989-matiere-et-complexite-9782350308753.html     Contact : Vincent Robert, équipe LCQ, Institut de Chimie de Strasbourg (UMR 7177).
  [En savoir plus]

mai 22 2023

Chem. Eur. J. [LCC]

Abstract Carbonylmetallates [m]−, such as [MoCp(CO)3]−, [Mn(CO)5]−, [Co(CO)4]−, have long been successfully used in the preparation of hundreds of metal-metal bonded carbonyl complexes and clusters, in particular of the heterometallic type. We focus here on situations where [m]− can be viewed as a terminal, doubly or even triply bridging metalloligand, developing metal-metal interactions with...[En savoir plus]

mai 22 2023

Eur. J. Inorg. Chem. [CLAC]

Abstract: This article covers 50 years of coordination chemistry of transition metal complexes and metal-sulfur aggregates involving thiolate-incorporating ligands by reviewing selected examples. The studies in the coordination chemistry of sulfur-rich ligands have been undoubtedly triggered and fed by the concomitant development of bioinorganic chemistry, particularly of iron-sulfur enzymes....[En savoir plus]

mai 10 2023

Inorganic Chemistry [BCB/POMAN]

Abstract α-Pyridyl thiosemicarbazones (TSC) such as Triapine (3AP) and Dp44mT are a promising class of anticancer agents. Contrary to Triapine, Dp44mT showed a pronounced synergism with CuII, which may be due to the generation of reactive oxygen species (ROS) by Dp44mT-bound CuII ions. However, in the intracellular environment, CuII complexes have to cope with glutathione (GSH), a relevant CuII...[En savoir plus]

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