Chem. Commun. [POMAM]

Abstract :

FID-detected nutations of the antiferromagnetic crystal form of [Y(pc)₂]˙ demonstrated that its radical spin can be coherently driven in its magnetically condensed undeuterated phase and at room temperature. Liquid-helium nutations revealed additional Rabi oscillations assigned to transitions within higher-multiplicity states of finite-sized chain fragments.

Graphical Abstract:

 

Reference : 

Athanassios K. Boudalis, Jorge-Enrique Olivares-Peña, Eufemio Moreno-Pineda, Artem Fediai, Wolfgang Wenzel, Philippe Turek and Mario Ruben

Room-temperature spin nutations in a magnetically condensed phase of [Y(pc)₂]˙

Chem. Commun. , 2021 - DOI: https://doi.org/10.1039/D1CC05491K

Contact :

Athanassios K. Boudalis (https://pomam.chimie.unistra.fr/aboudalis/), POMAM, Institut de Chimie (UMR 7177).