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[LCIMC] Chimie inorganique moléculaire et catalyse

Secrétariat et gestion assurés par

Elisabeth VACCARO
courriel : vaccaro@unistra.fr
téléphone : 03 68 85 16 84

Personnels permanents

  • Claude BAUDER
    Maître de Conférences à l'UdS
    courriel :
    cbauder@unistra.fr
    téléphone : 03 68 85 16 17
  • David SEMERIL
    Chargé de Recherche au CNRS
    courriel : dsemeril@unistra.fr
    téléphone : 03 68 85 15 50
   

Personnels non permanents

Doctorants

  • Nallusamy NATARAJAN
  • Hamzé MALLAH

Descriptif de l'équipe de recherche

We are interested in all aspects of coordination, organometallic and metallo-supramolecular chemistry with a particular emphasis upon the synthesis of cavity-shaped ligands and their use in organometallic catalysis and green chemistry. Much of our work relies on macrocyclic molecules, such as calixarenes, resorcinarenes, and cyclodextrins. The latter may be used as receptors or serve as platforms for the construction of multifunctional podands.

         Beside ligand design the laboratory also focuses on homogeneous catalysis, this including topics such as hydroformylation, hydroaminovinylation, oligomerisation, polymerisation, cross coupling, asymmetric catalysis, etc.

 

Thèmes de recherche

  • Molecular containers and receptors
  • Metallocavitands for intra-cavity catalysis
  • Funnel complexes
  • Functionalisation of cyclodextrins, resorcarenes, calixarenes
  • Design of introverted ligands
  • Large chelators and strained ligands in homogeneous catalysis
  • Homogeneous catalysis
  • Hydroformylation and polymerisation of olefins
  • C,C- bond forming reactions (Suzuki-Miyaura, Heck, ...)
  • Asymmetric Catalysis with transition metals
  • Selective extractants and sensors based on macrocyclic compounds

 

Selected Publications of the Matt Group

M. TECI, E. BRENNER, D. MATT, C. GOURLAOUEN, L. TOUPET
"Hummingbird" behaviour of N-heterocyclic carbenes stabilises out-of-plane bonding of AuCl and CuCl units
Chemistry, Eur. J. (2015) 10997-11000 

T. CHAVAGNAN, D. SÉMERIL, D. MATT, J. HARROWFIELD,L. TOUPET
Cracking cavitands: Metal-directed scission of phosphinyl-substituted resorcinarenes
Chemistry, Eur. J. (2015) 6678-6681

D. SEMERIL, D. MATT
Synthesis and catalytic relevance of P(III) and P(V)-functionalised calixarenes and resorcinarenes
Coord. Chem. Rev.279 (2014) 58-95

R. GRAMAGE-DORIA, D. ARMSPACH, D. MATT
Metallated cavitands with internal coordination sites
Coord. Chem. Rev. 257 (2013) 776-816

N. SAHIN, D. SEMERIL, E. BRENNER, D. MATT, İ. ÖZDEMIR, C. KAYA, L. TOUPET
Resorcinarene-functionalised imidazolium salts as ligand precursors for palladium catalysed Suzuki-Miyaura cross-couplings
Chem. Cat. Chem. (2013) 1116-1125

M. TECI, E. BRENNER, D. MATT, L. TOUPET
N-heterocyclic carbenes functioning as monoligating clamps
Eur. J. Inorg. Chem. (2013) 2841-2848

R. GRAMAGE-DORIA, D. ARMSPACH, D. MATT, L. TOUPET
TRANSDIP, a trans-chelating ligand tailor-made for probing unusual Pd(0) and Pd(II) intermediates
Chemistry, Eur. J. 18 (2012) 10813-10816

Liste du matériel et des appareils

  • Gas chromatographs High performance liquid chromatograph
  • Fourier Transform InfraRed spectrometer
  • High pressure autoclaves

Galerie photos de l'équipe de recherche

Un petit aperçu de notre équipe de recherche