Vous êtes ici : Home   >   News : ChemCatChem [LSAMM]

ChemCatChem [LSAMM]

Sep 17 2020


Synergistic action in a bimetallic nanosized catalyst: A bimetallic catalyst consisting of a flexible molecular cage with two Co(III) porphyrins is investigated to convert CO2 and epoxides into cyclic carbonates. The preorganisation of the two metal centres in the hollow framework favours their intramolecular cooperative action leading to superior catalytic performance than for a Co(III) meso-tetraphenylporphyrin.

Graphical Abstract



Reference :

A flexible bis-Co(III) porphyrin cage as a bimetallic catalyst for the conversion of CO2 and epoxides into cyclic carbonates

Laetitia Schoepff, Laure Monnereau, Stéphanie Durot, Sébastien Jenni, Christophe Gourlaouen, and Valérie Heitz

ChemCatChem, first published 21 August 2020 -  DOI : https://doi.org/10.1002/cctc.202001176


Stéphanie Durot and Valérie Heitz , équipe LSAMM (http://www.lsamm.fr/), Institut de Chimie (UMR 7177).