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[SRCO] Synthèse, Réactivité et Catalyse Organométalliques

Head of the research group

Samuel DAGORNE
Directeur de Recherche au CNRS

Secretarial and accounting services provided by

Agnès REIFFSTECK
email: reiffste@unistra.fr
Phone : +33 (0)3 68 85 14 32

Permanent members

  • Samuel DAGORNE
    Directeur de Recherche CNRS
    email: dagorne@unistra.fr
    Phone: +33 (0)3 68 85 15 30
  • Béatrice JACQUES
    Maître de Conférence Unistra
    email: jacques@unistra.fr
    Phone: +33 (0)3 68 85 10 87
  • Pierre DE FREMONT
    Chargé de Recherche CNRS
    email : defremont@unistra.fr
    Phone: +33 (0)3 68 85 10 87
 

Non-permanent members

PhD students

  • Jean-Charles BRUYERE
  • Anaëlle BOLLEY
  • Yuri SOKOLOVICZ (en co-tutelle avec l'Univ. Porto Alegre, Brésil)

PostDocs

  • Refka GUERMAZI

Description of the group

The SRCO team broadly aims at the design and reactivity of novel organometallic complexes for small molecules activation (H2, CO2) and use in homogeneous catalysis, with a special emphasis on sustainable catalytic processes. 

Past/current industrial colloborations: Corbion-Purac Corp. (lactide polymerization), SNF Corp. (biodegradable hydrophilic polymers)

Our team welcomes internship applications at the Master level, potential candidates interested in PhD studies as well as post-doctoral candidates.   

Research topics

  • oxophilic metal complexes (groups 2, 4, 12 and 13) with N-heterocyclic carbenes (NHCs) for novel reactivity of fundamental interest,,
  • Small molecules (H2, CO2) activation (H2, CO2) with highly electrophilic organometallics based on Al(III), Zn(II) and Mg(II) salts,
  • Polymerization catalysis of cyclic esters/carbonates using organometallics for the production of biomaterials,
  • Organometallic complexes of Au(I)/Au(III) for use in homogeneous catalysis.

Selection of key publications

D. Specklin, F. Hild, C. Fliedel, C. Gourlaouen, L. F. Veiros, S. Dagorne
Chem. Eur. J.
2017, 23, 15908-15912

D. Specklin, C. Fliedel, C. Gourlaouen, J.-C. Bruyere, T. Avilés, C. Boudon, L. Ruhlmann, S. Dagorne
Chem. Eur. J.
2017, 23, 5509-5519

G. Schnee, O.N. Faza, D. Specklin, B. Jacques, L. Karmazin, R. Welter, C.S. Lopez, S. Dagorne
Chem. Eur J.,
2015, 21, 17959‑17972

B. Jacques, D. Hueber, M. Hoffmann, S. Hameury, P. Brausntein, P. Pale, A. Blanc, P. de Frémont
Organometallics 2014, 33, 2326–2335

Fliedel, C., Vila-Viçosa, D., Calhorda, M. J., Dagorne S., Avilés, T.
ChemCatChem
2014, 6, 1357