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[SRCO] Synthèse, Réactivité et Catalyse Organométalliques

Head of the research group

Samuel DAGORNE
Directeur de Recherche au CNRS

Location

Le Bel Institute, 9th floor North

Secretarial and accounting services provided by

Agnès REIFFSTECK
email: reiffste@unistra.fr
Phone : +33 (0)3 68 85 14 32

Permanent members

  • Samuel DAGORNE
    Directeur de Recherche CNRS
    email: dagorne@unistra.fr
    Phone: +33 (0)3 68 85 15 30
  • Béatrice JACQUES
    Maître de Conférence Unistra
    email: jacques@unistra.fr
    Phone: +33 (0)3 68 85 10 87
  • Pierre DE FREMONT
    Chargé de Recherche CNRS
    email : defremont@unistra.fr
    Phone: +33 (0)3 68 85 10 87
 

Non-permanent members

PhD students

  • Nicolas ADET
  • Xuejuan XU
  • Gaël PRINTZ
  • Jordan PARMENTIER
  • Neghmouche Nacer Salah (collaboration avec l’Univ. Constantine, Algérie)

PostDocs

  • Anaëlle BOLLEY

Assistant-Ingénieur (CDD)

  • Refka GUERMAZI

Description of the group

The SRCO team broadly aims at the design and reactivity of novel organometallic complexes for small molecules activation (H2, CO2) and use in homogeneous catalysis, with a special emphasis on sustainable catalytic processes. 

Past/current industrial colloborations: Corbion-Purac Corp. (lactide polymerization), SNF Corp. (biodegradable hydrophilic polymers)

Our team welcomes internship applications at the Master level, potential candidates interested in PhD studies as well as post-doctoral candidates.   

Research topics

  • oxophilic metal complexes (groups 2, 4, 12 and 13) with N-heterocyclic carbenes (NHCs) for novel reactivity of fundamental interest,,
  • Small molecules (H2, CO2) activation (H2, CO2) with highly electrophilic organometallics based on Al(III), Zn(II) and Mg(II) salts,
  • Polymerization catalysis of cyclic esters/carbonates using organometallics for the production of biomaterials,
  • Organometallic complexes of Au(I)/Au(III) for use in homogeneous catalysis.

Enseignement

Vous trouverez ci-dessous les 3 premiers cours M1 du Dr Samuel Dagorne.

Vous trouverez ci-dessous les cours L3 du Dr Samuel Dagorne.

Selection of key publications

Bruyere, J.-C.; Specklin, D.; Gourlaouen, C.; Lapenta, R.; Veiros, L. F.; Grassi, A.; Milione, S.; Ruhlmann, L.; Boudon, C.; Dagorne, S.
Cyclic(Alkyl)(Amino)Carbene (CAAC)-Supported Zn Alkyls: Synthesis, Structure and Reactivity in Hydrosilylation Catalysis
Chemistry – A European Journal
2019, 25 (34), 8061–8069 - DOI: https://doi.org/10.1002/chem.201900961
Cover feature:
S. Dagorne et al.

Bruyere, J.-C.; Gourlaouen, C.; Karmazin, L.; Bailly, C.; Boudon, C.; Ruhlmann, L.; de Frémont, P.; Dagorne, S.
Synthesis and Characterization of Neutral and Cationic Magnesium Complexes Supported by NHC Ligands
Organometallics 2019, 38 (14), 2748–2757 - DOI:  https://doi.org/10.1021/acs.organomet.9b00304

Dagorne, S.
Recent Developments on N-Heterocyclic Carbene Supported Zinc Complexes: Synthesis and Use in Catalysis
Synthesis 2018, 50 (18), 3662–3670 - DOI:  https://doi.org/10.1055/s-0037-1610088

Dagorne, S. Wehmschulte, R.
Recent Developments on the Use of Group 13 Metal Complexes in Catalysis
ChemCatChem 2018, 10 (12), 2509–2520 - DOI: http://onlinelibrary.wiley.com/doi/pdf/10.1002/cctc.201800045

D. Specklin, F. Hild, C. Fliedel, C. Gourlaouen, L. F. Veiros, S. Dagorne
Accessing Two‐Coordinate ZnII Organocations by NHC Coordination: Synthesis, Structure, and Use as π‐Lewis Acids in Alkene, Alkyne, and CO2 Hydrosilylation
Chem. Eur. J.
2017, 23, 15908-15912- DOI: https://onlinelibrary.wiley.com/doi/abs/10.1002/chem.201704382

D. Specklin, C. Fliedel, C. Gourlaouen, J.-C. Bruyere, T. Avilés, C. Boudon, L. Ruhlmann, S. Dagorne
N‐Heterocyclic Carbene Based Tri‐organyl‐Zn–Alkyl Cations: Synthesis, Structures, and Use in CO2 Functionalization
Chem. Eur. J.
2017, 23, 5509-5519 - DOI: https://www.onlinelibrary.wiley.com/doi/abs/10.1002/chem.201605907

G. Schnee, O.N. Faza, D. Specklin, B. Jacques, L. Karmazin, R. Welter, C.S. Lopez, S. Dagorne
Normal‐to‐Abnormal NHC Rearrangement of AlIII, GaIII, and InIII Trialkyl Complexes: Scope, Mechanism, Reactivity Studies, and H2 Activation
Chem. Eur J.,
2015, 21, 17959‑17972 - DOI: https://onlinelibrary.wiley.com/doi/abs/10.1002/chem.201503000

B. Jacques, D. Hueber, M. Hoffmann, S. Hameury, P. Brausntein, P. Pale, A. Blanc, P. de Frémont
Synthesis, Characterization, and Catalytic Activity of Cationic NHC Gold(III) Pyridine Complexes
Organometallics
2014, 33, 2326–2335 - DOI: https://pubs.acs.org/doi/10.1021/om400338k

Fliedel, C., Vila-Viçosa, D., Calhorda, M. J., Dagorne S., Avilés, T.
Dinuclear Zinc–N‐Heterocyclic Carbene Complexes for Either the Controlled Ring‐Opening Polymerization of Lactide or the Controlled Degradation of Polylactide Under Mild Conditions
ChemCatChem
2014, 6, 1357 - DOI: https://www.onlinelibrary.wiley.com/doi/abs/10.1002/cctc.201301015