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Actualités de l'institut

sept. 4 2018

Soutenance de thèse de Joel Montalvo

Soutenance de thèse de doctorat de Joel Montalvo Acosta Mardi 4 Septembre 2018 à 11h00, ISIS, salle de conférence. Titre : "Computational approaches to molecular recognition: From Host-Guest to Protein-Ligand binding" Directeur de thèse: Marco CECCHINI, IFM, Institut de Chimie.[En savoir plus]

août 22 2018

Chemical Reviews [LCQ]

Abstract : Intersystem crossing (ISC), formally forbidden within nonrelativistic quantum theory, is the mechanism by which a molecule changes its spin state. It plays an important role in the excited state decay dynamics of many molecular systems and not just those containing heavy elements. In the simplest case, ISC is driven by direct spin–orbit coupling between two states of different...[En savoir plus]

juil. 19 2018

Cover Chem. Eur. J. [LCC]

Cover abstract : Selective transmetallation from copper(I) or silver (I) to palladium(0) at P donors of the rigid multidentate ligand PCNHCP results when [M3(μ3‐PCNHCP)2](OTf)3 (M=Cu, Ag) reacts with [Pd(PPh3)4]. The graphic illustrates the double short‐bite nature of the ligand system that stabilizes the metal chain and favors attractive d10‐d10 closed‐shell interactions without restraining...[En savoir plus]

juil. 19 2018

JOC [LASYROC]

Abstract: The copper(I)-doped zeolite CuI−USY proved to be a versatile, efficient, and recyclable catalyst for various Ullmann-type coupling reactions. Easy to prepare and cheap, this catalytic material enables the arylation and heteroarylation of diverse O-, N-, S-, and C-nucleophiles under ligand-free conditions while exhibiting large functional group compatibility. The facility of this...[En savoir plus]

juil. 13 2018

PCCP [POMAM]

Summary : Magnetic dipole interactions are extensively used in NMR and EPR spectroscopies to probe interatomic distances between paramagnetic centers when crystal structures are not readily available. However, this usually concerns spin carriers whose spin density is fully localised, such magnetic nuclei, transition-metal ions and organic radicals. In this work we show that it is possible to...[En savoir plus]

juil. 4 2018

France-China Summer School in green chemistry

La première édition de l'Ecole d'été France-Chine en Chimie Verte se déroule à l'Université de Strasbourg du 2 au 21 juillet 2018. Piloté par l'Ambassade de France en Chine et Campus France (http://www.chine.campusfrance.org/fr/node/302374), le programme regroupe 10 étudiants Chinois et 1 étudiante brésilienne actuellement en cours de Master dans leur pays. L'idée est de leur faire découvrir...[En savoir plus]

juil. 3 2018

Cover Dalton Transactions [LCC, POMAM]

Abstract: The double aminolysis reaction of [Co{N(SiMe3)2}2] by the salt 1-(6-((dicyclohexylphosphaneyl)methyl)pyridin-2-yl)-3-(2,6-diisopropylphenyl)-1H-imidazol-3-ium bromide, which contains one phosphane, one pyridine and one imidazolium groups, of formula [o-Cy2PCH2(C5H3N)(o-C3H3N2DiPP)]Br and abbreviated as (CyPNpyrCim)Br, was previously shown to afford the Co(II) complex [Co(CyP*NaCNHC)Br]...[En savoir plus]