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Cover Chem. Eur. J. [LCC]

juil. 19 2018

Cover abstract :

Selective transmetallation from copper(I) or silver (I) to palladium(0) at P donors of the rigid multidentate ligand PCNHCP results when [M33PCNHCP)2](OTf)3 (M=Cu, Ag) reacts with [Pd(PPh3)4]. The graphic illustrates the double short‐bite nature of the ligand system that stabilizes the metal chain and favors attractive d10‐d10 closed‐shell interactions without restraining reactivity.


Reference :

Pengfei Ai, Kirill Yu. Monakhov, Jan van Leusen, Paul Kçgerler, Christophe Gourlaouen, Moniek Tromp, Richard Welter, Andreas A. Danopoulos, and Pierre Braunstein

Linear CuI2Pd0, CuIPd02, and AgI2Pd0 Metal Chains Supported by Rigid N,N’ Diphosphanyl N-Heterocyclic Carbene Ligands and Metallophilic Interactions

Chem. Eur. J. 2018, 24, 8787 – 8796, https://onlinelibrary.wiley.com/doi/abs/10.1002/chem.201802728

Contact chercheur :

Pierre Braunstein, LCC, Institut de Chimie (courriel : braunstein@unistra.fr) and Christophe Gourlaouen, LCQ, Institut de Chimie (courriel : gourlaouen@unistra.fr).