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Chemistry : A European Journal

mars 13 2018

Putting a (molecular) spin on copper catalysis: Metalloenzymes routinely perform multielectronic transformations using multistate reactivity and redox cofactors but this behavior is difficult to emulate in synthetic systems. We report a rare example of molecular spin catalysis in the context of copper-catalyzed aziridination. The molecular spin fluxionality enabled by the redox-active ligands is central to this behavior.

 drawing abstract

Référence :

Chem. Eur. J. 2018, doi: 10.1002/chem.201705649

Contact chercheur:

Marine DESAGE-EL MURR, Institut de Chimie de Strasbourg

Courriel : desageelmurr@unistra.fr