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Beilstein J. Org. Chem. [OMECA]

mai 29 2020

Abstract :

Copper catalysis finds applications in various synthetic fields by utilizing the ability of copper to sustain mono- and bielectronic elementary steps. Further to the development of well-defined copper complexes with classical ligands such as phosphines and N-heterocyclic carbenes, a new and fast-expanding area of research is exploring the possibility of a complementing metal-centered reactivity with electronic participation by the coordination sphere. To achieve this electronic flexibility, redox-active ligands can be used to engage in a fruitful “electronic dialogue” with the metal center, and provide additional venues for electron transfer. This review aims to present the latest results in the area of copper-based cooperative catalysis with redox-active ligands.

Reference :

A. Das, Y. Ren, C. Hessin and M. Desage-El Murr

Copper catalysis with redox-active ligands

Beilstein J. Org. Chem. 202016, 858-870 – DOI : 10.3762/bjoc.16.77

Contact chercheur :

M. Desage-El Murr, équipe OMECA (http://marinedesageelmurr.fr) , Institut de Chimie (UMR 7177).